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    Magnesium reacts with sulfuric acid:

    Question
    SLPaper 2

    Magnesium reacts with sulfuric acid:

    Mg(s) + H2SO4(aq) → MgSO4(aq) + H2(g)

    The graph shows the results of an experiment using excess magnesium ribbon and dilutesulfuric acid.

    M17/4/CHEMI/SP2/ENG/TZ2/05.a.i

    1.

    Outline why the rate of the reaction decreases with time.

    [1]
    Verified
    Solution

    concentration of acid decreases
    OR
    surface area of magnesium decreases

    Accept “less frequency/chance/rate/probability/likelihood of collisions”.

    Do not accept just “less acid” or “lessmagnesium”.

    Do not accept “concentrations ofreagents decrease”.

    1mark1 mark1mark

    2.

    Sketch, on the same graph, the expected results if the experiment were repeatedusing powdered magnesium, keeping its mass and all other variables unchanged.

    [1]
    Verified
    Solution

    curve starting from origin with steeper gradient AND reaching same maximumvolume

    1mark1 mark1mark

    3.

    Nitrogen dioxide and carbon monoxide react according to the following equation:

    NO2(g) + CO(g) ⇌ NO(g) + CO2(g) Δ_H_ = –226 kJ

    Calculate the activation energy for the reverse reaction.

    [1]
    Verified
    Solution

    «_E_a(rev) =226 +132 =» 358 «kJ»

    Do not accept –358.

    1mark1 mark1mark

    4.

    State the equation for the reaction of NO2 in the atmosphere to produceacid deposition.

    [1]
    Verified
    Solution

    2NO2(g) +H2O(l) → HNO3(aq) +HNO2(aq)
    OR
    2NO2(g) +2H2O(l) +O2(g) → 4HNO3(aq)

    Accept ionised forms of the acids.

    1mark1 mark1mark

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    Related topics

    6.1 Collision theory and rates of reaction5.3 Bond enthalpies8.5 Acid depositionR2.2 How fast? The rate of chemical changeR3.1 Proton transfer reactions
    Chemistry (Old)
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