The apparatus depicted in the diagram below was used by a student to examine how the pressure of air varies with volume while maintaining a constant temperature.
The air was confined in a tube with a uniform cross-sectional area, positioned above a column of oil.
The pump pushes oil up the tube, reducing the volume of the trapped air.
The student measured the height of the air column and the corresponding air pressure . After each decrease in volume, they paused for a while before recording the pressure. Outline why this step was necessary.
in order to keep the temperature constant
in to allow the system to reach thermal equilibrium with the surroundings
The following graph of versus was obtained. Error bars were negligibly small.
The equation of the line of best fit is .
Determine the value of including an appropriate unit.
recognizes as gradient
calculates in range to
Unit:
Outline how the results of this experiment are consistent with the ideal gas law at constant temperature.
thus ideal gas law gives
so graph should be a straight line through origin, as observed
The cross-sectional area of the tube is and the temperature of air is 295 K. Estimate the number of moles of air in the tube.
The equation in may be used to predict the pressure of the air at extremely large values of . Suggest why this will be an unreliable estimate of the pressure.