- Consider mixing salt in water versus sand in water:
- Saltwater looks clear and uniform.
- Sand in water looks cloudy, and the sand settles at the bottom.
- These differences come from particle size, visibility, and stability of the mixture.
- Chemists classify such mixtures as solutions, colloids, or suspensions.
- Solutions → very small particles (ions or molecules), fully dissolved.
- Colloids → medium-sized particles, dispersed but not dissolved.
- Suspensions → large particles, which can be seen and will settle.
| Key differences | Solutions | Colloids | Suspensions |
|---|
| Particle size | < 1 nm | 1-1000 nm | > 1000 nm |
| Visibility | Invisible | Visible under a microscope | Visible to the naked eye |
| Stability | Stable, never settles | Stable, rarely settles | Unstable, settles over time |
| Light scattering | Does not scatter light | Scatters light (Tyndall effect) | Does not scatter light |
| Filtration | Passes through filters | Passes through filters | Particles are trapped by filters |
- The Tyndall effect is the scattering of light by small particles in a mixture, making a light beam visible.
- It is a key property of colloids: they scatter light strongly enough for the beam to be seen.
- Solute → the substance being dissolved (usually in smaller amount).
- Solvent → the substance doing the dissolving (usually in larger amount).
Saltwater
- Solute: sodium chloride (salt)
- Solvent: water
- Particle size: < 1 nm (molecules or ions).
- Visibility: Individual particles cannot be seen, even with a light microscope.
- Uniformity: Completely uniform throughout – no lumps, layers, or floating bits.
- Stability: The solute never settles out on standing.
- Light scattering: Does not scatter light → no visible beam.
Colloids are:
- Heterogeneous at the microscopic level (non-uniform if you zoom in),
- But appear uniform to the naked eye.
- Particle size: approximately 1–1000 nm.
- Visibility: Particles are too small to see individually with the naked eye, but can be seen with a microscope.
- Stability: Particles do not settle out under normal conditions.
- Filtration: Colloidal particles pass through ordinary filter paper.
- Tyndall effect: Colloids scatter light, making a flashlight beam visible as it passes through.
Colloids in daily life
- Milk – an emulsion of tiny fat droplets in water.
- Fog – tiny water droplets dispersed in air.
- Gelatin – a network of solid particles in water.
- Emulsions are colloids where two liquids that don’t usually mix (like oil and water) are dispersed together.
- For example, mayonnaise is an emulsion of oil in water, stabilised by egg yolk.
Over time, these particles settle to the bottom under gravity.
- Particle size: > 1000 nm (can range up to millimetres).
- Visibility: Particles are easily seen with the naked eye.
- Non-uniformity: The mixture is clearly non-uniform.
- Instability: Particles settle on standing → forms a layer at the bottom.
- Filtration: Particles can be trapped by filter paper.
- Muddy water – soil or sand particles in water.
- Sand in water – sand quickly settles to the bottom.
- Some salad dressings – herbs or spices suspended in oil or vinegar, which separate into layers.
- To keep a suspension uniform, it must be shaken or stirred regularly.
- This re-distributes the particles and prevents them from sitting at the bottom.
Particle size affects:
- Visibility – whether we can see particles with our eyes.
- Stability – whether particles settle out.
- Behaviour – whether mixtures can be filtered or show the Tyndall effect.
Think of table salt versus sand:
- Salt dissolves completely in water and disappears – like a solution.
- Sand stays visible and settles – like a suspension.
Colloids sit in between these two extremes.
Scientists use simple experimental tests to decide what kind of mixture they are dealing with.
Method: Pour the mixture through filter paper.
Results:
- Solution:
- No residue on the filter.
- Filtrate is clear.
- Colloid:
- No residue on the filter (particles are too small).
- Filtrate may appear cloudy or translucent.
- Suspension:
- Solid particles remain on the filter paper.
- Filtrate (liquid that passes through) is clearer than the original mixture.
Method: Shine a narrow beam of light through the mixture in a dark room.
Results:
- Solution:
- Light passes through without scattering.
- The beam is not visible from the side.
- Colloid:
- Light is scattered by the particles.
- The beam becomes visible as a glowing path → Tyndall effect.
- Suspension:
- Large particles may block or reflect light, making the mixture look cloudy.
- However, the beam does not show a uniform glowing path as in a colloid.
Placeholder (diagram):
A light beam passing through three tubes labelled “solution”, “colloid”, and “suspension”. The beam is only clearly visible in the colloid tube (Tyndall effect).
Use a strong, narrow light source (e.g. laser pointer) to see the Tyndall effect clearly.
Method: Leave the mixture undisturbed and observe over time.
Results:
- Solution:
- No visible change.
- Particles remain evenly distributed.
- Colloid:
- Particles remain suspended and do not settle.
- The mixture stays cloudy or translucent.
- Suspension:
- Heavy particles settle to the bottom, forming a sediment.
- The upper liquid becomes clearer.
Combining all three tests – filtration, light scattering, and sedimentation – gives a reliable way to classify unknown mixtures.
Understanding solutions, colloids and suspensions helps explain the behaviour of many everyday products.
- Solutions:
- Solutions are uniform, so every sip of a drink or every dose of saline has the same composition.
- Dissolved substances can be absorbed easily by the body (e.g. in medical solutions).
- Colloids:
- Colloids stay mixed for a long time, so products like milk, creams, and paints don’t separate quickly.
- Their ability to scatter light can be useful (fog, smoke detection) or a problem (haze in drinks).
- Suspensions:
- Suspensions can be separated by filtration or settling, which is useful in water treatment.
- Some medicines are designed as suspensions so that the solid drug is released or absorbed gradually.
- In food, suspension behaviour affects texture and appearance.
- How do solutions, colloids, and suspensions differ in particle size, visibility, and stability?
- Give three real-life examples of each type of mixture.
- Explain why their specific properties (e.g. stability, visibility, ease of separation) are important for their function.
- Which technique do you think is most effective for distinguishing between solutions, colloids, and suspensions:
- Filtration,
- Tyndall effect, or
- Sedimentation?
- Explain your choice.