De Broglie Hypothesis, Particle Diffraction, and Compton Scattering
The De Broglie Hypothesis: Particles as Waves
- In 1923, Louis de Broglie proposed a revolutionary idea: particles, such as electrons or protons, can exhibit wave-like properties.
- He introduced the concept of the de Broglie wavelength, which relates a particle’s momentum to its wavelength: $$\lambda = \frac{h}{p}$$ where:
- $\lambda$ is the particle’s wavelength (in meters),
- $h$ is Planck’s constant $ 6.63 \times 10^{-34} \, \mathrm{J s} $,
- $p$ is the particle’s momentum $ p = mv $, where $ m $ is mass and $ v $ is velocity.
This hypothesis suggests that all moving particles, no matter how small or large, have an associated wavelength.
Why Does This Matter?
- The de Broglie hypothesis bridges the classical and quantum worlds.
- It shows that particles, which we often think of as discrete points, can behave like waves under certain conditions.
- This duality particles behaving as waves is a fundamental concept in quantum mechanics.
Particle Diffraction: Evidence for Wave Behavior
- If particles truly exhibit wave-like properties, we should be able to observe phenomena like diffraction and interference, which are characteristic of waves.
- This was experimentally confirmed in 1927 by the Davisson-Germer experiment.
The Davisson-Germer Experiment
- In this experiment, electrons were accelerated through a potential difference and directed at a nickel crystal.
- The scattered electrons produced a pattern of bright and dark spots, similar to the diffraction patterns seen with light waves passing through a slit.

The key finding: the spacing of the diffraction pattern matched the de Broglie wavelength of the electrons.
It is calculated using:
$$\lambda = \frac{h}{\sqrt{2m_e qV}}$$
where:
- $m_e$ is the electron’s mass $ 9.11 \times 10^{-31} \, \mathrm{kg} $,
- $q$ is the electron’s charge $ 1.60 \times 10^{-19} \, \mathrm{C} $,
- $V$ is the accelerating voltage.



