Second law of thermodynamics
The Second Law of Thermodynamics states that in any energy transformation, some of the energy is lost as heat and becomes less available to do useful work.
- The Second Law of Thermodynamics states that energy transformations are inefficient and that in every transformation, some energy is degraded into a less useful form, typically heat.
- This law relates to the quality of energy, not its quantity.
- Although the total energy in a system remains constant (as per the First Law), the amount of usable energy decreases after each transformation.
- In ecosystems, the largest energy losses occur during cellular respiration, when chemical energy from food is transformed into heat.
Energy Degradation in Ecosystems
- Energy enters ecosystems as concentrated light from the Sun (a high-quality energy form).
- Through photosynthesis, this is converted into chemical energy in biomass.
- As organisms use this energy (through respiration, growth, movement, etc.), much is released as heat.
- Thus, with each transformation, energy disperses, increasing entropy (disorder) in the system.
Entropy
Entropy refers to the measure of disorder or randomness within a system.
- When a rabbit consumes a plant, only a small fraction of the chemical energy in the plant is converted into useful energy for the rabbit’s movement, growth, and reproduction.
- The rest is lost as heat through metabolic processes.
Energy Transformations and Inefficiency in Ecosystems
- Energy enters ecosystems in a concentrated form (solar radiation) and gradually becomes dispersed as it moves through trophic levels.
- At each stage:
- Producers absorb only a small portion of incoming solar energy due to reflection, transmission, and inefficiency of photosynthesis.
- Consumers and decomposers lose energy through respiration, excretion, and movement.
- Heat is the most significant form of energy degradation.
- In ecosystems, the largest energy losses occur during cellular respiration, where chemical energy is converted into work and heat.
Only about 10% of the energy from one trophic level is passed to the next level, with the remaining 90% being lost mainly as heat or waste.
Exam techniqueWhen asked to “explain why energy transfers are inefficient,” always link your answer to heat loss during respiration and the Second Law of Thermodynamics.
Ecological Efficiency and Energy Availability
- Ecological efficiency measures how much energy is transferred from one trophic level to the next.
- Formula:
$$\text{Ecological efficiency} = \frac{\text{Energy used for growth (new biomass)}}{\text{Energy supplied}} \times 100$$ - Typically, this value ranges between 5%-20%, with an average of 10% in most ecosystems.
- This inefficiency limits biomass production at higher trophic levels and determines ecosystem carrying capacity.
Consumers Obtain Energy from Producers or Other Organisms
Consumers
Consumers are organisms that obtain chemical energy by consuming other organisms or organic material.
- Consumers are organisms that obtain energy and matter by feeding on other organisms.
- They are heterotrophs, unable to produce their own food because they lack photosynthetic pigments like chlorophyll.
- Consumers depend on carbon-containing organic compounds (e.g., carbohydrates, fats, proteins) synthesized by autotrophs.
- They play a crucial role in transferring chemical energy and matter through food chains and webs.
Consumers link primary producers to decomposers, forming a continuous flow of energy and cycling of matter within ecosystems.
Types of Consumers and Their Energy Strategies
1. Herbivores
Herbivores
Herbivores are animals that feed primarily on plants or algae.
- Feed directly on producers (plants or algae).
- Represent primary consumers in food chains.
- Possess specialized teeth, digestive tracts, or symbiotic bacteria to break down cellulose.
- A hippopotamus grazes on aquatic vegetation.
- Cows and zebras also rely on plant matter for energy.
Specify that herbivores obtain chemical energy originally derived from sunlight stored in plant biomass.
2. Detritivores
Detrivores
Detritivores are organisms that feed on dead organic matter, such as decaying plants and animals.
- Feed on dead organic matter (detritus) such as fallen leaves, feces, and carcass fragments.


