Alloys: Enhanced Materials Through Metallic Bonding
Alloy
An alloy is a mixture of a metal with one or more other elements, which can be either metals or non-metals
- Unlike compounds, where elements are chemically bonded in fixed ratios, alloys are physical mixtures.
- They are typically created by melting the components together and allowing the mixture to solidify.
- The resulting material often has properties that are superior to those of the pure metal.
Key Features of Alloys:
- Improved Strength: Alloys are often harder and stronger than their pure metal counterparts.
- Corrosion Resistance: Many alloys resist rust and oxidation better than pure metals.
- Tailored Properties: By adjusting the composition, alloys can be designed for specific applications, such as electrical conductivity, heat resistance, or malleability.

Metallic Bonding and Alloy Properties
To understand why alloys have such remarkable properties, we need to revisit the concept of metallic bonding.
Metallic bonding
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions.
- In pure metals, atoms are arranged in a regular lattice, and their outer electrons are delocalized, forming a sea of electrons that flows freely throughout the structure.
- This delocalized electron cloud gives metals their characteristic properties, such as electrical conductivity and malleability.
Non-Directional Bonding in Metals
- Metallic bonds are non-directional, meaning the attraction between the positive metal ions and the delocalized electrons is uniform in all directions.
- This allows metal atoms to slide past each other without breaking the bond, which is why pure metals are often soft and malleable.
Why Alloys Are Stronger
- The irregular arrangement of atoms in alloys makes it harder for the layers of atoms to slide past each other.



