The Structure of Fatty Acids: A Quick Overview
- All fatty acids share a common structure: a long hydrocarbon chain (a chain of carbon atoms bonded to hydrogen) with a carboxyl group (-COOH) at one end. However, these chains can vary in two key ways:
- Length: The number of carbon atoms in the chain (typically between 14 and 20 in biological systems).
- Saturation: The number and position of double bonds between carbon atoms.
The term "saturation" refers to how many hydrogen atoms are bonded to the carbon chain:
- Saturated fatty acids: No double bonds. Every carbon atom is fully "saturated" with hydrogen atoms.
- Unsaturated fatty acids: One or more double bonds between carbon atoms. These are further divided into:
- Monounsaturated fatty acids (MUFA): Contain one double bond.
- Polyunsaturated fatty acids (PUFA): Contain two or more double bonds.
Saturated Fatty Acids: The Straight Chains
Characteristics
- No double bonds: A rigid, linear structure.
- High melting point: Tightly packed molecules require more energy (heat) to separate, making saturated fats solid at room temperature.
- Sources: Found in animal fats (e.g., butter, lard) and some plant oils like coconut oil.
- Stearic acid: A saturated fatty acid with 18 carbon atoms and no double bonds.
Biological Role
- Saturated fats are ideal for long-term energy storage and thermal insulation in animals.
- For example, marine mammals like whales rely on blubber, rich in saturated fatty acids, to retain heat in cold waters.
- Don’t assume "saturated" automatically means "unhealthy."
- While excessive intake is linked to health risks, saturated fats play essential roles in energy storage and insulation.
Monounsaturated Fatty Acids: The First Bend
Analogy- Now, considere a rope with a single knot.
- This is how monounsaturated fatty acids (MUFA) appear, a single double bond introduces a "kink" in the chain, preventing tight packing.
Characteristics
- One double bond: The kink reduces the molecule’s ability to stack.
- Moderate melting point: MUFAs are typically liquid at room temperature but may solidify when cooled.
- Sources: Found in plant-based oils like olive oil, avocado oil, and nuts.
- Oleic acid: A monounsaturated fatty acid with 18 carbon atoms and one double bond.
Biological Role
- MUFAs are common in plant oils, which are liquid at room temperature.
- These oils provide energy storage in seeds and are easier to mobilize during germination.
- Think of olive oil: its liquid state at room temperature is due to the "kink" introduced by monounsaturated fatty acids.
- Why does a single double bond in monounsaturated fatty acids prevent them from being solid at room temperature?


