The Origin and Structure of Earth's Atmosphere
Earth's Lost Atmosphere
- During its early formation, Earth was surrounded by a cloud of silicate vapor.
- As the planet cooled, this vapor condensed into molten and solid rock.
- Any remaining gases from the solar nebula, such as hydrogen, were swept away by the solar wind, leaving Earth without an atmosphere.
Formation of Earth's Present Atmosphere
Outgassing
- Outgassing refers to the release of gases trapped within Earth's interior.
- As Earth cooled and formed a solid crust, volcanic eruptions continued to release gases such as:
Water vapor (\$\text{H}_2\text{O}\$)
Carbon dioxide (\$\text{CO}_2\$)
Hydrogen sulfide (\$\text{H}_2\text{S}\$)
Nitrogen (\$\text{N}_2\$)
These gases formed the basis of Earth's early atmosphere.
Cometary Impacts
- Comets and other icy bodies from the outer solar system also contributed to Earth's atmosphere.
- These impacts released volatile materials such as:
Water
Carbon dioxide
Methane (\$\text{CH}_4\$)
Ammonia (\$\text{NH}_3\$)
Cometary impacts likely added significant amounts of water and other gases to Earth's atmosphere.
Development of Earth's Atmosphere
A Reducing Atmosphere
Earth's early atmosphere was reducing, meaning it lacked oxygen.
Key processes included:
- Dissolution of carbon dioxide: \$\text{CO}_2\$ dissolved in oceans and formed limestone.
- Photochemical reactions: Ultraviolet radiation split water molecules into hydrogen and oxygen.
- Oxygen removal: Oxygen reacted with minerals and volcanic gases, preventing accumulation.
This atmosphere was dominated by gases like carbon dioxide, methane, and ammonia.
An Oxidizing Atmosphere
The evolution of photosynthetic organisms (e.g., cyanobacteria) marked a turning point.
Photosynthesis released oxygen as a byproduct:
- \$\$6\text{CO}_2 + 6\text{H}_2\text{O} \rightarrow \text{C} 6\text{H}{12}\text{O}_6 + 6\text{O}_2\$\$
- Oxygen levels increased, forming an oxidizing atmosphere.
This allowed the formation of the ozone layer (\$\text{O}_3\$), which protected life from harmful UV radiation.
An Aerobic Atmosphere
Over time, oxygen levels rose to support aerobic organisms.
A balance emerged between:
- Photosynthesis: Producing oxygen.
- Respiration: Consuming oxygen.
This balance has maintained oxygen levels at approximately 21% for the past billion years.
The Structure of Earth's Atmosphere
The Composition of Air
Dry air consists mainly of:
- Nitrogen (\$\text{N}_2\$): 78%
- Oxygen (\$\text{O}_2\$): 21%
- Argon (\$\text{Ar}\$): ~1%
- Trace gases: Carbon dioxide, methane, neon, helium, and others.
Water vapor content varies from 0% in deserts to 4% in tropical regions.
Layers of the Atmosphere
The atmosphere is divided into four main layers based on temperature changes:
1. Troposphere
- Altitude: 0–11 km
- Temperature: Decreases with altitude.
- Features: Contains most of the atmosphere's mass and all weather phenomena.
2. Stratosphere
- Altitude: 11–50 km
- Temperature: Increases with altitude due to ozone absorption of UV radiation.
- Features: Contains the ozone layer, which protects life from UV rays.
3. Mesosphere
- Altitude: 50–85 km
- Temperature: Decreases with altitude.
- Features: Coldest layer; meteors burn up here.
4. Thermosphere
- Altitude: 85–600 km
- Temperature: Increases with altitude due to absorption of solar radiation.
- Features: Contains the ionosphere, which reflects radio waves and enables communication.
The boundaries between these layers are marked by pauses:
- Tropopause: Between the troposphere and stratosphere.
- Stratopause: Between the stratosphere and mesosphere.
- Mesopause: Between the mesosphere and thermosphere.